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the freeze-drying process comprises the following steps, preparing a liquid and filling at the temperature of 20-30 ℃, putting a sample into a freeze dryer, quickly reducing the temperature of a plate layer to-40 ℃, preserving heat for 1h, when the temperature of a partition plate is-10 +/-2 ℃, preserving heat for 1h, quickly reducing the temperature of the plate layer to-40 ℃ within 1h, preserving heat for 3h, transferring to a cold trap at-50 ℃, vacuumizing to below 10Pa, firstly preserving the temperature of the plate layer at-5 ℃ for 3h, then heating the plate layer to 10 ℃ within 3h, when a product is at 0 ℃, starting to increase the temperature of the plate layer to 40 ℃, and when the temperature of the product is increased to 30 ℃, preserving heat for 3 h